Syntheses Involving Organometallic and Organometalloidal Compounds Containing Polyfluoro and Polychloro Substituents

Abstract

The primary objective was concerned with new or improved syntheses of organometallic and organometalloidal compounds containing polyfluoro and polychloro substituents. These versatile reagents are to be used for the preparation of thermally stable fluids, lubricants, etc. One of the goals is to make available organometallic compounds of general types such as CF3(CF2)n-M and M-(CF2)n-M, in which M represents a metal or a metalloid. In addition, perhaloorganometallic compounds containing heteronuclear systems such as pyridine and thiophene have been studied. These two studies admirably complement each other, for there has been developed from the perhalogenated thiophenes some novel and highly promising routes to the perhalogenated alkanes.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1970
Accession Number
AD0887614

Entities

People

  • Dalbir S. Sethi
  • Henry Gilman
  • M. T. Rahman
  • Milton R. Smith Jr

Organizations

  • Iowa State University

Tags

Communities of Interest

  • Advanced Electronics
  • C4I

DTIC Thesaurus Topics

  • Alkanes
  • Chemical Products
  • Chemical Reactants
  • Chemical Synthesis
  • Chemistry
  • Hydroforming (Mechanical)
  • Hydroxides
  • Magnesium Alloys
  • Mass Spectrometry
  • Materials
  • Materials Laboratories
  • Organic Chemistry
  • Organometallic Compounds
  • Organosilicon Compounds
  • Sodium Compounds

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry