Research and Development of Flow-Cast Magnesium Flares

Abstract

Research and development studies have been conducted on flow-castable magnesium-sodium nitrate flares. The epoxy resins XFS-4008L (glycerin diglycidyl ether) and diglycidyl carbonate were evaluated. The curing agents XF-4012 (partial nitrate salt of amine-terminated polypropylene glycol), maleic anhydride (MA), maleic anhydride-ethylene carbonate (EC), maleic half esters, glycol, benzyldimethylamine and D.E.H. 24 (triethylenetetramine) were investigated. TEGDN (triethyleneglycol dinitrate), DEGDN (diethyleneglycol dinitrate), and BDNPA/F, 1-1-solution of bis-(2,2-dinitropropyl) acetal and bis(2,2-dinitropropyl) formal, were tested as plasticizers. The most favourable results were obtained with XFS-4008L resin; XF-4012, MA, EC-MA, or D.E.H. 24 curing agent; and TEGDN or DEGDN plasticizer. Flare compositions containing these binders can be mixed, poured, and cured; display low spark or impact sensitivity; and are adequately stable in storage at 70 C for 4 to 12 weeks. A 'best efforts' composition, containing 22 percent of XFS-4008L - EC-MA - DEGDN binder, yielded an efficiency of 70,000 cd-sec/g (candle-seconds per gram) at 0. 056 in/sec (inch per second) burning rate in a 1.25-inch-diameter tape-wrapped flare.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1971
Accession Number
AD0902122

Entities

People

  • Donald Girardin
  • Erwin M. Jankowiak
  • George A. Lane

Tags

Communities of Interest

  • Human Systems
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Facilities
  • Anhydrides
  • Biomedical And Dental Materials
  • Burning Rate
  • Chemistry
  • Combustion
  • Epoxy Resins
  • Ethylene Glycol
  • Materials
  • Materials Laboratories
  • Materials Science
  • Particle Size
  • Plasticizers
  • Resins
  • Test And Evaluation
  • Viscosity

Readers

  • Polymer Science and Engineering.
  • Rocket Propulsion.
  • Toxicology/Environmental Toxicology