Research on Synthesis Procedures for Intermediates Required for High Temperature Stable Polymers

Abstract

Work is reported on the synthesis and/or characterization of 30 different compounds for use in studies related to the preparation of high- temperature stable polymers. As a result of this effort, 28 synthesized and/or characterized compounds were submitted as 42 individual samples. The number and type of compounds submitted are identified as follows: Perfluoro-n-alkyl iodides; Divinyl substituted aromatics; Organo-diiodides; Acenaphthene derivatives; Diether linked dicarboxylic acids; Aromatic Disulfonamides; Perfluoroalkylene bisphenols; Perfluorophenyl thiols; Ladder polymer; Substituted polyphenyl ethers; and Substituted phenyl halides. The 42 samples of the submitted compounds ranged in size drom 2.0 to 650.4 g and, in nearly all cases, the purity was at least 99%. Mass spectrometry, infrared spectroscopy, gas liquid chromatography, nuclear magnetic resonance spectroscopy, thin-layer chromatography, differential thermal analysis, viscosimetry, and elemental analysis were employed to establish structure and determine purity.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1972
Accession Number
AD0902857

Entities

People

  • C. C. Chappelow Jr.
  • C. W. Kruse
  • G. L. Whittier
  • J. F. Engel

Organizations

  • MRIGlobal

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Alcohols
  • Alkanes
  • Alkenes
  • Anhydrides
  • Chlorides
  • Chromatography
  • Differential Thermal Analysis
  • High Temperature
  • Materials
  • Materials Laboratories
  • Methanols
  • Physical Properties
  • Plastic Explosives
  • Propionic Acid
  • Spectra
  • Spectroscopy
  • Thermal Analysis

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology