Demonstration of Ambient Temperature Cure.

Abstract

Four propellants are being optimized for ambient temperature processing and cure. These are (1) an 88 wt% solids 0.40 ips at 1000 psia burning rate R-45M propellant, (2) an 88 wt% solids 1.70 + or - 0.20 ips at 1000 psia burning rate R-45M propellant, (3) an 88 wt% solids 0.40 ips at 1000 psia burning rate propellant based on a Li-HTPB binder, and (4) an 86 wt% solids 0.40 ips at 1000 psia burning rate propellant based on a Telagen CTPB binder cured with epoxides. Two catalyst systems have been evaluated with the propellants containing the R-45M binder. These were ZnO/linoleic acid and ZnO/Fe(AA)3/benzilic acid/HAA. Of these two, the ZnO/linoleic acid system was selected for the scale up studies. The 0.40 ips at 1000 psia burning rate formulation has been successfully scaled up through 30 gallon mix size. The 1.70 + or - 0.20 ips at 1000 psia burning rate propellant has been optimized for ambient temperature cure in one gallon mixes. Two catalyst systems are being optimized for ambient temperature cure and processing in the 88% solids Li-HTPB propellant. These are ZnO/dibutyltin dilaurate/benzilic acid and ZnO/Fe(AA)3/benzilic acid/HAA. Satisfactory ambient temperature processing and cures have been achieved with the tin catalyst. Satisfactory ambient temperature processing and cures have been achieved with the Telagen CTPB propellant using Cr octoate catalyst. This propellant has been successfully scaled up through 30 gallon mix size. (Author)

Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1972
Accession Number
AD0905526

Entities

People

  • Edmond J. Mastrolia
  • H. J. Michigian

Organizations

  • Aerojet Rocketdyne Holdings

Tags

DTIC Thesaurus Topics

  • Burning Rate
  • Catalysts
  • Chemical Reactions
  • Combustion
  • Demonstrations
  • Exothermic Reactions
  • Linoleic Acid
  • Propellants

Readers

  • Polymer Science and Engineering.
  • Rocket Propulsion.