Structure-Property Relationships for Polycyanurate Networks Derived from Renewable Resources

Abstract

The recent synthesis of a wide variety of cyanate ester monomers that may be derived from renewable resources has created a newly available set of chemical structures that, due to a wide range of chemical features, provide a unique opportunity for the development of quantitative structure-property relationships for dicyanate esters and their polymerized networks. Specific structure-property relationships for monomer melting point, glass transition temperature at full conversion, and char yields at 600 degrees C under nitrogen and air have been developed with the aid of partial least squares methods. The predictions inherent in these structure-property relationships are examined and compared to predictions based on ordinary least squares methods. Specific predictions for the properties of two as-yet unsynthesized dicyanate ester monomers derived from renewable resources are also presented

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Document Details

Document Type
Technical Report
Publication Date
Jun 18, 2015
Accession Number
AD1001411

Entities

People

  • Andrew J. Guenthner
  • Andrew P. Chafin
  • Benjamin G Harvey
  • Heather A. Meylemans
  • Joseph M Mabry
  • Matthew C. Davis
  • Michael D. Ford
  • Michael E. Wright

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Conversion
  • Data Science
  • Data Sets
  • Glass
  • Glass Transition Temperature
  • Information Science
  • Least Squares Method
  • Materials
  • Melting
  • Melting Point
  • Military Research
  • Nitrogen
  • Regression Analysis
  • Transition Temperature
  • Transitions

Fields of Study

  • Chemistry

Readers

  • Computational Modeling and Simulation
  • Energy Conservation and Renewable Energy Engineering.
  • Organic Chemistry