Mass Spectral Studies of 1-(2-Chloroethoxy)-2-[(2-chloroethyl)thio] Ethane and Related Compounds Using Gas ChromatographyMass Spectrometry and Gas ChromatographyTriple-Quadrupole Mass Spectrometry

Abstract

The electron impact and collision-induced-dissociation mass spectra of 1-(2-chloroethoxy)-2-[(2-chloroethyl)thio] ethane and 10 related molecules were obtained using gas chromatographymass spectrometry and gas chromatographytriple-quadrupole mass spectrometry. These mass spectral studies were performed to facilitate the development of a spectral database of mustard-related compounds for verification purposes in support of the Chemical Weapons Convention. The proposed fragmentation pathways of the individual molecules are reported with rationalizations for the most characteristic ions.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 2016
Accession Number
AD1003011

Entities

People

  • Fu-lian Hsu
  • Mark D Winemiller
  • Sue Y. Bae

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Arms Control Treaties
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemical Weapons
  • Chromatography
  • Collisions
  • Dissociation
  • Electrons
  • Fragmentation
  • Gas Chromatography
  • Mass Spectra
  • Mass Spectrometry
  • Molecules
  • Spectra
  • Spectrometry
  • Sulfur Compounds
  • Weapons

Fields of Study

  • Chemistry

Readers

  • Database Systems and Applications
  • Molecular Photonics/Laser Physics

Technology Areas

  • Microelectronics