Depth-Resolved Nanospray Desorption Electrospray Ionization Mass Spectrometry in Biofilms

Abstract

The goal of this project was to develop a nano-DESI sensor which can be used to obtain in situ, depth-resolved analyses of metabolites and possibly proteins from biofilms at different depth. A microcapillary system was developed and tested for this goal. The microcapillary system delivered a solvent (ethanol) from one capillary while the other capillary collected and transported a charged liquid to the mass spectrometer inlet. We tried different configurations of microcapillary systems and optimized follow rates and its operation. The project successfully demonstrated that a dual microcapillary system can be used to collect nanoliter sample from the biofilms at different depth. However, the microcapillary system also collected cells which failed its use for MS.

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Document Details

Document Type
Technical Report
Publication Date
Nov 16, 2015
Accession Number
AD1008200

Entities

People

  • Erhan Atci
  • Haluk Beyenal
  • Tim Ewing

Organizations

  • Washington State University

Tags

Communities of Interest

  • Sensors

DTIC Thesaurus Topics

  • Department Of Defense
  • Desorption
  • Electrode Holders
  • Electrospray
  • Electrospray Ionization
  • Flow Rate
  • Ionization
  • Mass Spectra
  • Mass Spectrometers
  • Mass Spectrometry
  • Mass Spectroscopy
  • Measurement
  • Spectra
  • Spectrometers
  • Spectrometry
  • Spectroscopy
  • Students

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Military/Explosive Ordnance Disposal (EOD) Technology
  • Software Engineering

Technology Areas

  • Biotechnology
  • Biotechnology - Bioremediation