General and Robust Strategies for Multifunctional Organic-Inorganic Nanocomposites via Direct Growth of Monodisperse Nanocrystals Intimately and Permanently Connected with Polymers

Abstract

The objectives of this proposal are to: (1) Synthesize a series of novel amphiphilic block copolymers with well-defined molecular architectures (i.e., star-like block copolymers, bottlebrush-like block copolymers, and Janus star-like block copolymers) and block ratios based on -cyclodextrin(-CD) by living polymerization techniques; (2) Craft a large variety of monodisperse plain and core/shell NPs and NRs as well as Janus NPs of different dimension, chemistry, and properties, which are intimately and permanently capped by polymers on their surface (i.e., forming organic-inorganic nanocomposites), by capitalizing on amphiphilic star-like, bottlebrush-like, and Janus star-like block copolymers as nanoreactors; and (3) Characterize and explore these multifunctional organic-inorganic nanocomposites by measuring their physical properties (e.g., dielectric, magnetic, magnetoelectric, and optical properties) for potential use in spintronic devices, capacitors, actuators, transducers, sensors, photocatalysis, and photonic devices that are anticipated to fill a critical need in future military.

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Document Details

Document Type
Technical Report
Publication Date
Apr 21, 2016
Accession Number
AD1008321

Entities

People

  • Zhiqun Lin

Organizations

  • Georgia Tech

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Alkenes
  • Alkynes
  • Biomedical And Dental Materials
  • Block Copolymers
  • Chemical Synthesis
  • Chemistry
  • Ethers
  • Hydroxides
  • Materials
  • Materials Processing
  • Materials Science
  • Nanotechnology
  • Optical Properties
  • Organic Chemistry
  • Polymer Chemistry
  • Solar Cells

Readers

  • Materials Science and Engineering.
  • Molecular and Cellular Biochemistry
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.

Technology Areas

  • Microelectronics