Optimizing Glassy Polymer Network Morphology for Nano-Particle Dispersion, Stabilization and Performance

Abstract

MWCNT nanocomposite aerospace prepolymers were successfully prepared in a one-step high volume process through the development of a new preparation approach based upon a high-shear continuous reaction method. The continuous reactor based upon two principle advancements in process engineering. 1. Chain extension prepolymer reactions including curative dissolution, toughener dissolution and controlled chain-extension reactions in the continuous reactor high temperature hot-zone to advance conversion, rheology and tack. 2. Simultaneous MWCNT dispersion and stabilization in the continuous reactor low temperature cold-zone leading to an increased viscosity and stabilization of MWCNTs within rheological regimes which inhibit re-agglomeration to aid in post processing stabilization of dispersion state through final cure.

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Document Details

Document Type
Technical Report
Publication Date
Oct 03, 2016
Accession Number
AD1018149

Entities

People

  • Jeffrey S. Wiggins

Organizations

  • University of Southern Mississippi

Tags

Communities of Interest

  • Advanced Electronics
  • Space

DTIC Thesaurus Topics

  • Carbon Nanotubes
  • Chemical Kinetics
  • Composite Materials
  • Dispersions
  • Energy Management
  • Engineering
  • Material Degradation Processes
  • Materials
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Mechanical Properties
  • Nanocomposites
  • Polymer Degradation
  • Process Engineering
  • Resins
  • Thermoplastic Resins

Readers

  • Combustion science or combustion engineering.
  • Nanocomposite Materials Science
  • Polymer Science and Engineering.

Technology Areas

  • Space