Artificial Oxide Heterostructures with Tunable Band Gap

Abstract

We have performed the joint experimental and theoretical studies towards the realization of tunable band-gap in artificial oxide multiferroic thin-films and heterostructures under epitaxial strain. In multiferroic oxides, the magnetic exchange interaction is crucially dependent on the hybridization between the magnetic cation and its surrounding oxygen cage. The above is an valence and conduction bands, as well as the band gap. In addition, the magnetic interaction can be also strongly coupled to the ferroelectric polar distortion through the metal-oxygen bonding angles and lengths. By using the coupling between magnetic and the ferroelectric orderings, the band structure, gap as well as the magnetic properties can be tuned by the epitaxial strain. We showed the tunable optical dielectric functions from the surface reconstruction and the epitaxial strain in CaMnO3 films by epitaxial growth. We also demonstrated that the functional properties inhexagonal LuFeO3 have its electronic and structural origins and can be tuned by epitaxial strain. Finally, we also proposed new design rule for room temperature artificial perovskite superlattice, which is closed related with the current topic.

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Document Details

Document Type
Technical Report
Publication Date
Dec 20, 2016
Accession Number
AD1023462

Entities

People

  • Xifan Wu

Organizations

  • Temple University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Band Gaps
  • Band Structures
  • Contracts
  • Crystal Lattices
  • Distortion
  • Electronic Mail
  • Energy Bands
  • Engineering
  • Films
  • Ground State
  • Magnetic Properties
  • Materials
  • Materials Science
  • Thermal Expansion
  • Thin Films

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene