Fast Reacting Nano Composite Energetic Materials: Synthesis and Combustion Characterization

Abstract

Energetic composites are mixtures of solid fuel and oxidizer particles that when combined offer higher calorific output than monomolecular explosives. The composites traditionally deliver energy as diffusion limited reactions and thus their power available from reaction is much smaller than any explosive. Yet, technology has advanced particle synthesis, and nanoparticles have become more readily available. The advent of nanoparticle fuels enables traditionally diffusive controlled reactions to transition towards kinetically dominant reactions. This transition results in faster reacting formulations that show promise of harnessing the power equivalent to a monomolecular explosive, but packaged as discretely separate fuel and oxidizer composites. This chapter will focus on developing an understanding of fundamental reaction dynamics associated with particulate media, in general. Once this foundational understanding is established, new strategies for designing aluminum fuel particles toward greater reactivity and thus faster reacting formulations will be presented. In addition to synthesis, several combustion characterization techniques will be examined to quantify combustion performance. All of this information will provide a basis for future research and applications involving aluminum based fuels in any energetic system (i.e., as an additive to liquid propellants or even explosive formulations).

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Document Details

Document Type
Technical Report
Publication Date
Aug 24, 2015
Accession Number
AD1024778

Entities

People

  • Keerti Kappagantula
  • Michelle L. Pantoya

Organizations

  • Texas Tech University

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Aluminum Oxides
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Energetic Materials
  • Energy Transfer
  • Exothermic Reactions
  • Fluoropolymers
  • Ignition
  • Materials Processing
  • Materials Science
  • Metallic Nanoparticles
  • Nanocomposites
  • Nanoenergetics
  • Nanoparticles
  • Nanotechnology

Readers

  • Nanoscale Plasmonic Nanotechnology
  • Rocket Propulsion.
  • Systems Analysis and Design

Technology Areas

  • Biotechnology