Formation Energies of Native Point Defects in Strained layer Superlattices (Postprint)

Abstract

We develop a theoretical approach that employs first-principles Hamiltonian, tight-binding Hamiltonian, and Greens function techniques to obtain energy levels arising from native point defects (NPDs) in InAs-GaSb and InAs-InAs1-x Sb x strained layer superlattice (SLS) systems. In particular, we consider 4 types of NPDs anion vacancy, cation vacancy, anion anti-site, cation anti-site, isoelectronic substitution at anion sites (Sb at As site and As at Sb site) in the InAs, GaSb compound regions, and additional three types of defectscation at the second anion site, second anion at the cation site, and second anion vacancy in InAs1 x Sb x alloy region of the SLS. For a selected few designs, we study NPDs both in the bulk region and near the interfaces of the SLS. We have considered 12 designs of InAs-GaSb systems and 2 designs of InAs-InAs 0.7 Sb 0.3 systems lattice matched to GaSb substrate. The calculated defect levels not only agree well with available measurements but also reveal the connection between mid-gap levels and specific NPDs. We further calculate defect formation energies both in compounds and for all superlattices considered above.

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Document Details

Document Type
Technical Report
Publication Date
Jun 05, 2017
Accession Number
AD1041793

Entities

People

  • Srini Krishnamurthy
  • Zhi-gang Yu

Organizations

  • Washington State University Spokane

Tags

DTIC Thesaurus Topics

  • Air Force
  • Air Force Facilities
  • Air Force Research Laboratories
  • Bulk Materials
  • Compound Semiconductors
  • Computational Chemistry Methods
  • Crystal Lattices
  • Detection
  • Energy
  • Energy Levels
  • Free Energy
  • Governments
  • Materials
  • Measurement
  • Point Defects
  • Superlattices
  • United States

Fields of Study

  • Materials science

Readers

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  • Quantum Chemistry
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