High Capacity Cathode and Carbon Nanotube-Supported Anode for Enhanced Energy Density Batteries

Abstract

The work evaluated high capacity cathodes along with high capacity anode materials such as silicon and germanium to reach lithium ion cell energy density of 400 Wh/kg. In addition, an approach of managing the amount of reversible lithium in a cell to prevent the anode potential from increasing to greater than the dissolution potential during near zero volt storage is introduced. Pouch cell demonstrations for mesocarbon microbead anode and lithium cobalt oxide and lithium rich cathodes show stability for days at near zero volts beginning of life; with no measured difference in capacity, rate capability, or cycling. Cathode coating technologies of aluminum phosphate on lithium cobalt oxide improves the discharge stability which can increase energy density. The benefits of carbon nanotube current collectors for anode deposition are evaluated and improved with alumina coatings.

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Document Details

Document Type
Technical Report
Publication Date
Sep 07, 2017
Accession Number
AD1045128

Entities

People

  • Anthony Leggiero
  • Brian J. Landi
  • Christopher Schauerman
  • Jason Staub
  • Kyle Crompton
  • Matthew Ganter

Organizations

  • Rochester Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force Research Laboratories
  • Aluminum Oxides
  • Carbon Nanotubes
  • Chemical Synthesis
  • Chemical Vapor Deposition
  • Chemistry
  • Energy Storage
  • Fullerenes
  • Geosynchronous Orbits
  • Low Earth Orbits
  • Manufacturing
  • Materials
  • Materials Science
  • Measurement
  • Oxides
  • Paper
  • Spacecraft

Fields of Study

  • Materials science

Readers

  • Battery Technology and Engineering
  • Nanocomposite Materials Science
  • Surface Engineering/Surface Coating Technology.