Rapid Assessment of Remedial Effectiveness and Rebound in Fractured Bedrock

Abstract

Fractured rock sites impacted, with chlorinated solvents such as tetrachloroethene (PCE) or trichloroethene (TCE), remain a significant environmental challenge for the Department of Defense. Efforts to apply in situ remedial technologies, such as chemical oxidation or bioaugmentation, have often proved challenging and/or unsuccessful with respect to attaining remedial objectives in fractured rock aquifers. This is because contaminant rebound typically is observed due to processes such as DNAPL dissolution, matrix back-diffusion, and/or release of contaminants from low permeability/bypassed fracture zones. Unfortunately, recognition that these remedial technologies are ineffective is typically not realized until after substantial time and resources have been expended via in situ pilot testing, and the mechanism(s) controlling the observed contaminant rebound often remain unidentified. This lack of understanding in the conceptual site model hinders effective site management, particularly with respect to designing an appropriate remedial approach and identifying the practical limits of remediation.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 2017
Accession Number
AD1048807

Entities

People

  • Charles E Schaefer
  • David R. Lippincott
  • Graig M. Lavorgna
  • Hararld Klammler
  • Kirk Hatfield

Tags

Communities of Interest

  • Air Platforms
  • Counter WMD
  • Energy and Power Technologies
  • Human Systems

DTIC Thesaurus Topics

  • Alkanes
  • Alkenes
  • Chemistry
  • Construction
  • Cost Analysis
  • Diffusion Coefficient
  • Digital Data
  • Digital Information
  • Environmental Pollutants
  • Geology
  • Groundwater
  • High Resolution
  • Identities
  • Mass Transfer
  • Materials Testing
  • Mathematics
  • Measurement
  • Metadata
  • Pull Tests
  • Test And Evaluation
  • Test Methods
  • Volatile Organic Compounds

Fields of Study

  • Environmental science

Readers

  • Groundwater Contamination Remediation.
  • Systems Analysis and Design