Rapid Assessment of Remedial Effectiveness and Rebound in Fractured Bedrock

Abstract

Fractured rock sites, impacted with chlorinated solvents such as tetrachloroethene (PCE) ortrichloroethene (TCE), remain a significant environmental challenge for the Department of Defense. Efforts to apply in situ remedial technologies, such as chemical oxidation or bio augmentation, have often proved challenging and/or unsuccessful with respect to attaining remedial objectives in fractured rock aquifers. Contaminant rebound typically is observed due to processes such as dense non-aqueous phase liquid (DNAPL) dissolution, matrix back-diffusion, and/or release of contaminants from low permeability/bypassed fracture zones. Unfortunately, the ineffectiveness of these remedial technologies is typically not recognized until after substantial time and resources have been expended via in situ pilot testing, and the mechanism(s) controlling the observed contaminant rebound often remain unidentified. This lack of understanding in the conceptual site model hinders effective site management, particularly with respect to designing an appropriate remedial approach and identifying the practical limits of remediation.

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Document Details

Document Type
Technical Report
Publication Date
Aug 16, 2017
Accession Number
AD1052679

Entities

People

  • Charles E Schaefer
  • David Lippincott
  • Harald Klammler
  • Kirk Hatfield

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Alkanes
  • Alkenes
  • Chemical Reactions
  • Chemistry
  • Cost Analysis
  • Cost Estimates
  • Department Of Defense
  • Drinking Water
  • Environment
  • Environmental Pollutants
  • Environmental Protection
  • Environmental Restoration And Remediation
  • Fatty Acids
  • Groundwater
  • Organic Compounds
  • Test Methods
  • Volatile Organic Compounds

Fields of Study

  • Environmental science

Readers

  • Economics
  • Groundwater Contamination Remediation.