An Oxygen-Sensitive Toxin-Antitoxin System

Abstract

The Hha and TomB proteins from Escherichia coli form an oxygen-dependent toxinantitoxin (TA) system. Here we show that YmoB, the Yersinia orthologue of TomB, and its single cysteine variant [C117S]YmoB can replace TomB as antitoxins in E. coli. In contrast to other TA systems, [C117S]YmoB transiently interacts with Hha (rather than forming a stable complex)and enhances the spontaneous oxidation of the Hha conserved cysteine residue to a -SOxH containing species (sulfenic, sulfinic or sulfonic acid), which destabilizes the toxin. The nuclear magnetic resonance structure of [C117S]YmoB and the homology model of TomB show that the two proteins form a four-helix bundle with a conserved buried cysteine connected to the exterior by a channel with a diameter comparable to that of an oxygen molecule. The Hha interaction site is located on the opposite side of the helix bundle.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Dec 08, 2016
Accession Number
AD1053491

Entities

People

  • Ainara Morera
  • Irene Amata
  • Jesus Garcia
  • Joao M. Teixeira
  • Marina Gay
  • Marta Vilaseca
  • Maxim Mayzel
  • Miquel Pons
  • Oriol Marimon
  • Thammajun L. Wood
  • Thomas K. Wood
  • Tiago N. Cordeiro
  • Valerie W. Soo
  • Vladislav Y. Orekhov

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Amino Acids
  • Anti-Bacterial Agents
  • Chemical Engineering
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Dihedral Angle
  • Environment
  • Liquid Chromatography
  • Magnetic Resonance
  • Mass Spectrometry
  • Organic Chemistry
  • Spectra
  • Spectrometry
  • Spectroscopy
  • Three Dimensional
  • Toxicity

Fields of Study

  • Biology

Readers

  • Microbial Pathology
  • Molecular and Cellular Biochemistry
  • Organic Chemistry