Extremely High Quantum Efficiency and High Purity Rare-Earth-Doped Crystals for Solid-State Laser Cooling: Material Synthesis and Characterization

Abstract

This project concerned investigating the growth and characterization of extremely high-purity low-phonon energy crystals doped with rare-earth ions (ytterbium, thulium and holmium). The overall goals are: (1) achieving lower temperatures (approaching 70K and beyond), (2) improving efficiency, and (3) enhancing the cooling power (density). The recent record cooling studies have been obtained in high-purity Yb-doped YLiF4 (YLF) crystals. Further advances in this field should address material selection and synthesis involving (a) smaller ground state manifold splitting (Stark splitting), (b) higher doping concentration without degrading the external quantum efficiency (EQE), (c) the use of dopants with smaller energy gap such as Tm, Ho and Dy, and (d) mitigation of parasitic absorption by identifying the impurity source and purifying the starting materials. In this project, we closely collaborate with Dr. Markus Hehlen at Los Alamos National Laboratory (LANL) who is the world leading material scientist in RE-doped crystals for optical refrigeration.

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Document Details

Document Type
Technical Report
Publication Date
Oct 05, 2018
Accession Number
AD1062408

Entities

People

  • Mansoor Shelk-bahae
  • Markus P Hehlen

Organizations

  • University of New Mexico

Tags

Communities of Interest

  • Energy and Power Technologies
  • Sensors

DTIC Thesaurus Topics

  • Absorption Coefficients
  • Absorption Spectra
  • Climate Change
  • Crystal Growth
  • Crystals
  • Detectors
  • Emission Spectra
  • Energy
  • Ground State
  • Low Temperature
  • Measurement
  • Optical Properties
  • Optics
  • Quantum Efficiency
  • Spectra
  • Temperature Gradients
  • Thermal Conductivity

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Research Science/Academic Research

Technology Areas

  • Directed Energy
  • Quantum Computing