Structure, Morphology, Property Relationships in Polyisobutylene-Based Triphasic Block Copolymers Containing Hydrophilic/Functional Block Elements

Abstract

1. Develop new, modular synthetic methods toward PIB-based barrier materials with three different micro-architectures (Figures MG1 and MG2). 2. Probe the relative importance of composition vs. architecture as a determinant of observed morphology and associated barrier and moisture transmission properties of PIB-based thermoplastic elastomers containing hydrophilic blocks. 3. Characterize barrier performance and water transmission capabilities of synthesized membranes (in collaboration with Natick). 4. Determine the most effective hydrophilic block among several proposed candidates including poly(acrylic acid), poly(ethylene oxide), and poly(ethylene imine). 5. Obtain continued support for this effort through collaboration with Army scientists at Natick and scientists at Defense Threat Reduction Agency (DTRA).

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Document Details

Document Type
Technical Report
Publication Date
Jun 12, 2018
Accession Number
AD1063239

Entities

People

  • Robson F. Storey

Organizations

  • University of Southern Mississippi

Tags

Communities of Interest

  • C4I
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Acetonitrile
  • Acrylic Acid
  • Alcohols
  • Alkenes
  • Alkynes
  • Block Copolymers
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Copolymers
  • Elastomers
  • Equations
  • Ethylene Oxide
  • Ethylenes
  • Explosives Initiators
  • Films
  • Hydrophilic Properties
  • Materials
  • Methanols
  • Methylenes
  • Mississippi
  • Moisture
  • Molecular Weight
  • Organic Chemistry
  • Polymers
  • Scientists

Fields of Study

  • Materials science

Readers

  • Nanocomposite Materials Science
  • Polymer Science and Technology
  • Technical Research and Report Writing.

Technology Areas

  • Microelectronics