Doping Of Diamond beyond Thermodynamic Solubility Limit For Electronic Applications

Abstract

We have achieved a proof of concept for n- and p-doping of diamond based on the recently discovered direct conversion of amorphous carbon into diamond at ambient temperatures and pressures in air. The key advantage stems from the novel growth approach, where the carbon layers are melted by using high-power nanosecond pulsed lasers in a highly super undercooled state, and then quenched rapidly either into a new state of carbon (Q-carbon) or into the single-crystal diamond phase in the presence of a template for diamond growth. Accordingly, it is envisioned that dopant impurities present in the amorphous carbon films can be incorporated into substitutional (electrically active) sites of diamond during rapid liquid-phase crystallization via the phenomenon of solute trapping.

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Document Details

Document Type
Technical Report
Publication Date
Nov 05, 2018
Accession Number
AD1067398

Entities

People

  • Jagdish Narayan

Organizations

  • North Carolina State University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Crystals
  • Diffraction
  • Electron Energy
  • Electron Microscopy
  • Electronic Mail
  • Electrons
  • Energy
  • Films
  • Liquid Phases
  • Materials
  • Materials Science
  • Partial Pressure
  • Raman Spectroscopy
  • Semiconductors
  • Single Crystals
  • Spectroscopy
  • Thin Films

Readers

  • Materials Science and Engineering.
  • Powder metallurgy of Titanium alloys.
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics