Synthesis and Acetylcholinesterase Assay Report for RS182A and RS150D

Abstract

The synthesis and the reactivation kinetics of two cholinergic reactivators, RS150D and RS182A, are reported, and the results are compared to the kinetics of the standard reactivator, 2-pyridine aldoxime methyl chloride (2-PAM). In a 2011 article, Sit and his coworkers highlighted RS150D as a promising reactivator of ethyl N,N-dimethyl phosphoramidocyanidate (GA)-inhibited acetylcholinesterase (AChE), although it was not found to perform better than the standard 2-PAM reactivator. The reaction schemes for RS150D and RS182A are described, and the kinetic assays with several agents are reported. The synthesis produced acceptable overall yields.

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Document Details

Document Type
Technical Report
Publication Date
Jan 31, 2018
Accession Number
AD1070683

Entities

People

  • Andrew J. Walz
  • James Myslinski
  • Jude Height

Organizations

  • Edgewood Chemical Biological Center

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Acetylcholinesterases
  • Albumins
  • Central Nervous System
  • Chemical Synthesis
  • Chemical Warfare Agents
  • Chemistry
  • Chlorides
  • Department Of Homeland Security
  • Enzymes
  • Inhibition
  • Inhibitors
  • Kinetics
  • Nerve Agents
  • Pyridines
  • Standards
  • Therapy
  • Vx Agent

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Neurotoxicology