Transport in Complex Crystalline Materials Based on van der Waals Heterostructures

Abstract

A dearth of high-quality 2-D semiconductors and the difficulty of scaling down 3-D semiconductors have severely limited the prospects for the development of next-generation energy efficient electronic devices. To overcome these challenges, we have developed a technique to integrate van der Waals 2-D and conventional 3-D semiconductors. Our resultant novel 2-D/3-Dheterostructure consists of molybdenum disulfide as the 2-D component encapsulated between 3-D gallium nitride in a vertical configuration. This ultra-thin structure is a promising material system as a component of an improved heterojunction bipolar transistor (HBT). High-quality, defect-free interfaces between the 2- and 3-D systems, a critical criterion for efficient HBT device operation, was achieved through chemical powder vaporization, metal-organic chemical vapor deposition, and molecular beam epitaxy. We also synthesized a trilayer 3-D/2-D/3-D semiconductor structure (the first demonstration of itskind), validated all major critical aspects of the design, and performed a feasibility study of our design and microfabrication process for a functional HBT model. In particular, 2-D/3-D diode behavior was demonstrated for the fully synthesizedheterostructures built without mechanical transfer. The outcomes of this basic research effort could pave the way for explorations into the novel physics of 2-D materials for energy-efficient electronics devices and systems.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 2019
Accession Number
AD1078381

Entities

People

  • A. Glen Birdwell
  • Dmitry Ruzmetov
  • Edward F. C. Byrd
  • Mahesh R. Neupane
  • Matthew L. Chin
  • Michael D. Valentin
  • Robert A. Burke
  • Ryan Enck
  • Tony Ivanov

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Band Structures
  • Chemical Synthesis
  • Chemical Vapor Deposition
  • Chemistry
  • Computational Chemistry Methods
  • Electronics Industry
  • Electronics Laboratories
  • Energy Bands
  • Modules (Electronics)
  • P-N Junctions
  • Power Electronics
  • Semiconductor Devices
  • Semiconductors
  • Silicon Carbide
  • Three Dimensional
  • Two Dimensional
  • Two-Dimensional Materials

Fields of Study

  • Materials science

Readers

  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Systems Analysis and Design

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene