Computational and experimental analysis of short peptide motifs for enzyme inhibition

Abstract

The metabolism of living systems involves many enzymes that play key roles as catalystsand are essential to biological function. Searching ligands with the ability to modulateenzyme activities is central to diagnosis and therapeutics. Peptides represent a promisingclass of potential enzyme modulators due to the large chemical diversity, and well-establishedmethods for library synthesis. Peptides and their derivatives are found to play criticalroles in modulating enzymes and mediating cellular uptakes, which are increasingly valuablein therapeutics. We present a methodology that uses molecular dynamics (MD) andpoint-variant screening to identify short peptide motifs that are critical for inhibiting beta-galactosidase(beta-Gal). MD was used to simulate the conformations of peptides and to suggestshort motifs that were most populated in simulated conformations. The function of the simulatedmotifs was further validated by the experimental point-variant screening as critical segmentsfor inhibiting the enzyme.

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Document Details

Document Type
Technical Report
Publication Date
Aug 15, 2017
Accession Number
AD1082539

Entities

People

  • Anthony J. Cooper
  • Azka Ahmed
  • Jinglin Fu
  • John W. Whittaker
  • Junhao Dong
  • Luca Larini
  • Minyoung Lee
  • Ting Zhang

Organizations

  • Rutgers University–Camden

Tags

DTIC Thesaurus Topics

  • Acids
  • Amino Acids
  • Chemical Synthesis
  • Chemistry
  • Dynamics
  • Equations Of Motion
  • Inhibition
  • Inhibitors
  • Kinetics
  • Molecular Dynamics
  • Molecules
  • New Jersey
  • Nucleic Acids
  • Simulations
  • Small Molecules
  • United States
  • Universities

Fields of Study

  • Biology

Readers

  • Computer Engineering
  • Molecular Genetics
  • Molecular and Cellular Biochemistry