Standardizing Polymeric Sampling for Measuring Freely-Dissolved Organic Contaminants in Sediment Porewater

Abstract

Polymeric samplers sorb hydrophobic organic contaminants present in sediment, whether used actively or passively (i.e. respectively with or without sediment/polymer mixing). The resultant polymer concentrations can then be used to calculate freely dissolved contaminant concentrations (Cfree) in the sediments porewater. Polymeric samplers maybe used as alternatives to (a) Henry samplers and pumping for porewater sample collection or (b) sediment centrifugation with supernatant collection. Cfree measured by polymeric samplers represents the fraction of contaminants not sorbed to settling solids or associated with suspended colloidal matter. Cfree is directly linked tosediment-dwelling organisms exposure to contaminants as well as risk for biouptake intothe larger foodweb. Therefore, developing standardized methods for obtaining Cfreemeasurements using polymeric samplers is critically important.

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Document Details

Document Type
Technical Report
Publication Date
Oct 19, 2018
Accession Number
AD1084245

Entities

People

  • Adesewa Aribidara
  • Danny Reible
  • John Macfarlane
  • Mandar Bokare
  • Mandy Michalsen
  • Mingta Lin
  • Philip Gschwend
  • Upal Ghosh

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Accuracy
  • Aromatic Hydrocarbons
  • Aromatic Polycyclic Hydrocarbons
  • Chlorides
  • Computer Programs
  • Contracts
  • Cyclic Hydrocarbons
  • Department Of Defense
  • Environmental Protection
  • Gas Chromatography
  • High Resolution
  • Hydrocarbons
  • Mass Spectrometry
  • Measurement
  • Organic Compounds
  • Polychlorinated Biphenyls
  • Test Methods

Fields of Study

  • Environmental science

Readers

  • Agricultural Chemistry/Soil Science
  • Groundwater Contamination Remediation.
  • Systems Analysis and Design