Holistic Analysis of Emissions From a Modular Fast Pyrolysis System for Conversion of Biomass and Mixed Waste

Abstract

Fast pyrolysis of municipal solid waste (MSW) provides an alternative to open burn pits and MSW incinerators, which emit harmful gaseous emissions and particulate matter. Fast pyrolysis converts MSW to a primarily liquid product (i.e., bio-oil), which burns cleaner than solid MSW. To demonstrate the benefits of processing MSW using pyrolysis, we measured emissions from three different burners fueled by pyrolysis bio-oil, char, and gas and compared the results to standards set by the EPA regarding emissions from waste incinerators. Five of the EPA regulated pollutants (dioxins/furans, Cd, Pb, Hg, and HCl) were not observed during testing as they typically depend on feedstock composition (Cd, Pb, Hg, HCl) or are greatly reduced by burning liquid fuels (dioxins/furans). The pyrolysis system also met carbon monoxide, nitrogen oxide, and sulfur dioxide emissions standards at 10.6 ppm, 16.8 ppm, and 2.3 ppm respectively. PM emissions exceeded EPA limits at 60 mg/m3 versus 30 mg/m3. However, PM emissions are easily reduced by using a baghouse filter adjusting the bio-oil burner air-to-fuel ratio. These results clearly demonstrated that pyrolysis can convert MSW to power/heat while also meeting EPA emissions standards without using air pollution control systems.

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Document Details

Document Type
Technical Report
Publication Date
Apr 20, 2020
Accession Number
AD1088821

Entities

People

  • Alex D. Paulsen
  • Andrew L. Wagner
  • Michael J. Blaise
  • Nicholas R. Schwartz
  • Paul E. Yelvington

Tags

Communities of Interest

  • Biomedical
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Pollution
  • Air Pollution Control Systems
  • Beds (Process Engineering)
  • Calorific Value
  • Carbon Monoxide
  • Combustion
  • Combustion Products
  • Control Systems
  • Dielectric Gases
  • Diesel Fuels
  • Fossil Fuels
  • Liquids
  • Materials Laboratories
  • Measurement
  • Particle Size
  • United States

Fields of Study

  • Environmental science

Readers

  • Environmental Engineering.
  • Materials Science and Engineering.
  • Organic Chemistry