Effect of Elevated Fuel Cell Operating Temperature (120 deg C and 140 deg C) and Membrane Thickness on Proton Conductivity for Combat Vehicle Use

Abstract

Electrical power required to operate vehicles in the U.S. Army is increasing due to expanding mission requirements, such as silent watch, exportable power, and powerful onboard electronics. Proton Exchange Membrane Fuel Cells (PEMFCs) provide a solution, but stack thermal-cycling, electrocatalyst and membrane degradation losses need to be reduced before integration of PEMFCs can be realized. Membrane thermal degradation is exacerbated by poor heat rejection (as ballistic grills impede airflow) which can raise stack temperatures greater than or equal to 140 deg C. Commercial PEMFCs operate tilde 65 deg C so elevated temperatures could degrade the membrane. Nafion 115 (127 micrometer), 117 (183 micrometer) and 1110 (254 micrometer) membranes submerged in 16 M omega water were heated between 65-140 deg C to investigate elevated temperature and membrane thickness on proton conductivity. EIS results showed sample thickness did not statistically impact conductivity overall. Conductivity, however, was impacted for temperatures greater than 100 deg C with each material. Overall, these materials are not suitable when operating PEMFCs above 100 deg C.

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Document Details

Document Type
Technical Report
Publication Date
Feb 04, 2020
Accession Number
AD1091761

Entities

People

  • Theodore E. Burye

Organizations

  • United States Army Tank Automotive Research, Development and Engineering Center

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Cells
  • Combat Vehicles
  • Conductivity
  • Degradation
  • Diseases And Disorders
  • Electrocatalysts
  • Electronics
  • Energy
  • Energy Storage
  • Environment
  • Failure Analysis
  • Frequency Response
  • Fuel Cells
  • Ground Vehicles
  • Materials
  • Measurement
  • Membranes
  • Micrometers
  • Particle Size
  • Polymers
  • Rejection
  • Resistance
  • Thickness
  • United States
  • Vehicles
  • X-Ray Diffraction

Readers

  • Battery Technology and Engineering
  • Electrical Engineering
  • Thermal Physics or Thermal Science.

Technology Areas

  • Biotechnology
  • Microelectronics