Fundamental Investigation of Dynamic Phenomena in Atomically Thin Layered Materials

Abstract

Major Goals: The major goals of this research are to investigate novel thermodynamic phenomena of atomically thin layered materials, and to elucidate the interplay between local structures and dynamic behaviors as well as external field effects, by developing time-dependent in situ scanning probe techniques, combined scanning tunneling microscopy (STM) and atomic force microscopy (AFM). The proposed research aims to provide fundamental understanding of the mechanisms governing dynamic processes in two-dimensional (2D) materials. Results obtained from this project will be applied to mass transport, growth, shaping, site-specific heterogeneous catalysis, and gas sensing, and will have significant and broad impact on national security by providing predictive information regarding stability, reliability, and lifetime of devices based on 2D materials, and also for optimizing preparation of 2D materials. Accomplishments: We have successfully reached these goals. During the whole report period, we have published 12 peer reviewed papers in high impact journals, such as JACS, Nano Letters, Angew. Chem, ACS Nano., etc. (1-12), presented 15 conference presentations in national and international conferences, and received 4 awards. Below are the research activities were performed during the whole period and the highlight of our remarkable accomplishments. In the first year of ARO support, we have investigated the interfaces in mono- and few-layered MoS2, TiSe2 and graphene. We have made several remarkable observations about these systems, including unique edge states of MoS2 and charge density waves in TiSe2. We have performed experiments on monolayer vacancy island growth induced by a vertical electrical field on TiSe2, which is the beginning of studying dynamic properties of atomically thin TMDs. These layered materials were prepared on various substrates, including insulating substrates such as SiO2 and sapphire.

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Document Details

Document Type
Technical Report
Publication Date
Jul 31, 2019
Accession Number
AD1092418

Entities

People

  • Chenggang Tao

Organizations

  • Virginia Tech

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Band Gaps
  • Charge Carriers
  • Charge Density
  • Chemical Vapor Deposition
  • Compound Semiconductors
  • Density Functional Theory
  • Dynamics
  • Fullerenes
  • Materials
  • Materials Science
  • Monomolecular Films
  • Phase Transformations
  • Quantum Information
  • Self Assembly
  • Semiconductors
  • Two Dimensional
  • Two-Dimensional Materials

Fields of Study

  • Physics

Readers

  • Nanocomposite Materials Science
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene