Indentation Study of 2D Carbides for Manufacturing Novel Multifunctional Composites

Abstract

Two-dimensional (2D) materials beyond graphene are attracting much attention. Recently, we discovered a new family of 2D transition metals carbides and carbonitrides called MXenes. Unlike graphene, MXene family is very diverse and to date the number of synthesized MXenes reaches 17 members, including Ti3C2, Nb2C, V2C, Ta4C3, Cr2TiC2, Mo2TiC2, etc. Although MXenes have shown very attractive electrical, electrochemical properties, their mechanical properties are yet to be characterized. There are neither experimental measurements reported in literature nor prediction of strength and fracture modes for single-layer MXenes. In this 9-month research study, we took the first steps to investigate MXenes mechanical properties in both theoretical and experimental aspects. Molecular dynamics was used to predict stress-strain curves of all Tin+1Cn MXenes under tensile deformation. In addition, atomic force microscopy on Ti3C2 flakes and nanoindentation on Ti3C2-polymer composite films were performed to experimentally characterize MXenes mechanical properties.

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Document Details

Document Type
Technical Report
Publication Date
Oct 07, 2015
Accession Number
AD1100953

Entities

People

  • Vadym N Mochalin
  • Vadym N. Borysiuk
  • Yury Gogotsi

Organizations

  • Drexel University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Elastic Properties
  • Electron Microscopy
  • Manufacturing
  • Materials
  • Materials Science
  • Mechanical Properties
  • Microscopy
  • Modulus Of Elasticity
  • Molecular Dynamics
  • Physical Chemistry
  • Resins
  • Stress Strain Relations
  • Stresses
  • Transition Metals
  • Two-Dimensional Materials

Fields of Study

  • Materials science

Readers

  • Nanocomposite Materials Science
  • Powder metallurgy of Titanium alloys.
  • Riverine Ecology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene