Designing in the Face of Uncertainty: Exploiting Electronic Structure and Machine Learning Models for Discovery in Inorganic Chemistry

Abstract

Recent transformative advances in computing power and algorithms have made computational chemistry central to the discovery and design of new molecules and materials. First-principles simulations are increasingly accurate and applicable to large systems with the speed needed for high-throughput computational screening. Despite these strides, the combinatorial challenges associated with the vastness of chemical space mean that more than just fast and accurate computational tools are needed for accelerated chemical discovery. In transition-metal chemistry and catalysis, unique challenges arise. The variable spin, oxidation state, and coordination environments favored by elements with well-localized d or f electrons provide great opportunity for tailoring properties in catalytic or functional (e.g., magnetic) materials but also add layers of uncertainty to any design strategy.

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Document Details

Document Type
Technical Report
Publication Date
Mar 05, 2019
Accession Number
AD1105730

Entities

People

  • Aditya Nandy
  • Chenru Duan
  • Fang Liu
  • Heather J. Kulik
  • Jon P. Janet
  • Sean Lin
  • Tzuhsiung Yang

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Autonomy
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Algorithms
  • Chemical Engineering
  • Chemical Reactions
  • Chemistry
  • Computational Chemistry
  • Computational Chemistry Methods
  • Computational Science
  • Databases
  • Density Functional Theory
  • Inorganic Chemistry
  • Machine Learning
  • Materials
  • Materials Science
  • Molecular Dynamics
  • Neural Networks
  • Organic Chemistry
  • Transition Metals

Readers

  • Computational Fluid Dynamics (CFD)
  • Organic Chemistry
  • Systems Analysis and Design

Technology Areas

  • AI & ML
  • AI & ML - Machine Learning Algorithms
  • Microelectronics
  • Space