Predicting M4 Carbine Pollutant Emissions: Baseline Skeletal Finite-Rate Chemical Kinetics Mechanisms for Muzzle-Blast Modeling

Abstract

To create baseline chemical kinetics mechanisms for a computational fluid dynamics (CFD) model of M4 muzzle blast, the trial mechanism method was employed to reduce a full mechanism comprising 2751 elementary reactions and 813 species. The full mechanisms appropriateness for the application is discussed. Solutions to relevant homogeneous reactor problems based on skeletal mechanisms with as few as 22 reactions and 20 species yielded temperature and heat release rate versus time histories that well reproduced those produced with the full mechanism. Two candidates were recommended for use in the muzzle-blast CFD model: one with 22 reactions and 20 species, and one with 27 reactions and 22 species. All the inputs needed to construct them are provided in an addendum to this report (ARL-TN-1048). Targeting the establishment of better-designed screening protocols for future mechanism reduction efforts, recommendations for mapping the results of muzzle-blast simulations produced with these mechanisms are proffered.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 2021
Accession Number
AD1124833

Entities

People

  • Chiung-chu Chen
  • John R. Schmidt
  • Kevin L. McNesby
  • Michael J. McQuaid

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Kinetics
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Combustion Products
  • Composite Propellants
  • Computational Fluid Dynamics
  • Dielectric Gases
  • Dynamics
  • Fluid Dynamics
  • Hydroxyl Terminated Polybutadiene
  • Kinetics
  • Materials Laboratories
  • Materials Testing
  • Oxidation
  • Propellants
  • Propelling Charges
  • Reaction Mechanisms
  • Rocket Oxidizers
  • Simulations

Readers

  • Combustion science or combustion engineering.
  • Computational Modeling and Simulation
  • ballistics.