Cost Effective Destruction of Per- and Polyfluoroalkyl Substances from DoD Subsurface Investigation Derived Wastes Using a New Class of Adsorptive Photocatalysts

Abstract

The overall goal of this SEED project was to develop an innovative "Concentrate- and -Destroy" technology for cost-effective degradation of PFAS from DoD's subsurface investigation-derived wastes. The key findings are: 1) three novel adsorptive photocatalysts were synthesized, characterized and tested based on commercially available low-cost materials; 2) The new materials not only offer superior adsorption rate and capacity for PFAS (PFOA and PFOS), but also great photocatalytic degradation and mineralization efficiency; 3) The in situ efficient photodegradation of PFAS also regenerates the materials, allowing for repeated uses of the photocatalysts without chemical regeneration; and 4) Dilute Corexit EC9500A can serve as an effective, environmentally safe extractant for removing PFAS from soil. Based on the compelling preliminary findings, more in-depth follow on studies are warranted to further optimize the new materials and to test the technology under DoD field conditions.

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Document Details

Document Type
Technical Report
Publication Date
Apr 21, 2020
Accession Number
AD1134359

Entities

People

  • Dongye Zhao

Organizations

  • Auburn University

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical
  • Energy and Power Technologies
  • Sensors

DTIC Thesaurus Topics

  • Chemical Engineering
  • Chemical Products
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Composite Materials
  • Ecology
  • Ecotoxicology
  • Electron Microscopy
  • Energy Consumption
  • Liquid Chromatography
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Organic Chemistry
  • Spectra
  • Spectroscopy

Readers

  • Agricultural Chemistry/Soil Science
  • Internal Combustion Engine (ICE) Technology.
  • Systems Analysis and Design