Pilot Scale Assessment of a Deployable Photocatalytic Treatment System Modified with BiPO4 Catalyst Particles for PFAS Destruction in Investigation-Derived Wastewaters

Abstract

The BOHP/UV photocatalytic advanced oxidation process was developed at Clemson and previously shown via bench testing to rapidly mineralize PFOA in pure waters. The objectives of this limited scope project were to assess the capabilities of the treatment method for a wider range of PFAS contaminants relevant to IDW, identify important complex water matrix considerations and quenching species, and demonstrate performance of the catalyst upon incorporation into a deployable commercial photoreactor system. Furthermore, BOHP's lack of activity toward PFSAs warranted pursuit of a complimentary photocatalytic process to address this important subclass of PFAS contaminants. Photocatalytic reduction of PFOS by BiPO4 and GaOOH semiconductor particles was thus examined through bench experiments and one pilot test.

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Document Details

Document Type
Technical Report
Publication Date
Jan 31, 2020
Accession Number
AD1134389

Entities

People

  • Ezra L Cates

Organizations

  • Clemson University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Advanced Oxidation Processes
  • Band Gaps
  • Band Structures
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Department Of Defense
  • Ecology
  • Energy Bands
  • Liquid Chromatography
  • Mixing
  • Nanoparticles
  • Physical Chemistry
  • Self Assembly
  • Silica Glass
  • Water Purification
  • Water Quality

Fields of Study

  • Environmental science

Readers

  • Groundwater Contamination Remediation.
  • Nanocomposite Materials Science
  • Systems Analysis and Design

Technology Areas

  • Microelectronics
  • Microelectronics - Microelectromechanical Systems