Measuring and Predicting the Natural and Enhanced Rate and Capacity of Abiotic Reduction of Munition Constituents. Determining Properly Normalized Second Order Rate Constants and Reactive Reductant Concentrations: Limited Reductant Kinetic Experiments
Abstract
An experimental methodology utilizing limited reductant kinetic experiments is proposed that can be analyzed using the solution (Eq. 25 or 27) of the kinetic Eqs. 14 and 17. The results are second order rate constants and the quantity of reductant available at the experimental conditions of the reaction. These parameters can then be used to investigate which of the experimental conditions are affecting magnitude of the second order rate constant, the reductant concentrations and the resulting first order rate constant.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 31, 2019
- Accession Number
- AD1134954
Entities
People
- Dominic M. Di Toro
- Herbert E Allen
- Jimmy Murillo Gelvez
- Kevin P Hickey
- Paula Cardenas Hernandez
- Pei Chiu
Organizations
- University of Delaware