Plasmon-Induced Chemical Bond Cleavage by Refractory Transition Metal Nitrides

Abstract

This report presents research conducted by NRL Chemistry Division on plasmon-mediated photocatalysis by refractory transition metal nitrides (RTMNs). RTMN materials are synthesized, characterized by a variety of physico-chemical methods and utilized for evaluation of their photocatalytic activity in two reactions: (1) methanol photoelectrochemical oxidation at the electrode/solution interface and (2) oxidation of 2-chloro ethyl sulfide at the photocatalyst/air interface. The mechanisms of promotions are proposed.

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Document Details

Document Type
Technical Report
Publication Date
Oct 14, 2021
Accession Number
AD1150853

Entities

People

  • Albert Epshteyn
  • Andrew P Purdy
  • Blake S Simpkins
  • Olga Baturina
  • Spencer L. Giles

Organizations

  • United States Naval Research Laboratory

Tags

DTIC Thesaurus Topics

  • Alcohols
  • Chemical Bonds
  • Chemical Reactions
  • Chemistry
  • Department Of Defense
  • Information Operations
  • Material Degradation Processes
  • Materials
  • Materials Laboratories
  • Materials Science
  • Metallic Nanoparticles
  • Metals
  • Methanols
  • Nanomaterials
  • Nanoparticles
  • Nanostructures
  • Nanowires
  • Optical Properties
  • Oxidation
  • Plasmonic Materials
  • Surface Plasmon Resonance
  • Transition Metals
  • Transitions

Fields of Study

  • Chemistry

Readers

  • Nanoscale Plasmonic Nanotechnology
  • Quantum Chemistry
  • Surface Engineering/Surface Coating Technology.