Molecular Dynamics Analysis and Optimization of Ultra-High-Temperature Ceramic (UHTC) Compositions for Propulsion

Abstract

In this project, atomistic simulations were performed to analyze the material properties of ultra-high-temperature ceramics (UHTCs) for their use in aero-propulsion. Through mechanical testing and the use of the Green-Kubo formulation, the mechanical and thermal properties of transition metal borides ZrB2 and HfB2 are obtained using the classical molecular dynamics simulations code LAMMPS (Large-scale Atomic/Molecular Massively Parallel Simulator) and the bond-order Tersoff potential. These results show how the material properties of the UHTCs change with increasing temperature. The surface oxidization of single-crystal and polycrystalline silicon carbide is determined using the ReaxFF reactive interatomic potential. The simulations in this work were performed in the temperature range of 26-2000 deg C. The findings from this work evaluate the influence of extreme environments and the volatilization of molecules from the UHTC surface due to oxidization; however, further analysis of the oxidization of UHTCs would need the use of newly parameterized reactive potentials.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 2022
Accession Number
AD1171344

Entities

People

  • Anindya Ghoshal
  • Douglas E. Wolfe
  • Luis Bravo
  • Muthuvel Murugan
  • Robert Slapikas

Organizations

  • United States Army

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Abstracts
  • Carbides
  • Ceramic Materials
  • Ceramic Matrix Composites
  • Chemical Compounds
  • Compound Semiconductors
  • Crystal Structure
  • Crystals
  • Department Of Defense
  • Dynamics
  • Extreme Environments
  • High Performance Computing
  • High Temperature
  • Materials
  • Materials Science
  • Mechanical Properties
  • Military Research
  • Molecular Dynamics
  • Silicon Carbide
  • Simulations
  • Simulators
  • Single Crystals
  • Transition Metals
  • Ultra-High-Temperature Ceramics

Fields of Study

  • Materials science
  • Physics

Readers

  • Computational Modeling and Simulation
  • Quantum Chemistry
  • Surface Engineering/Surface Coating Technology.