Random Forest Permutation Feature Importance for Feature Selection in Ion Mobility Spectrometry

Abstract

Machine learning (ML) can be used to classify the spectra generated in ion mobility spectrometry (IMS)-based chemical detectors when they are used in the detection of explosives, chemical warfare agents, and other volatile hazardous compounds. The spectra of an IMS detector are composed of drift time bins (x axis) and their corresponding amplitudes (y axis). These values represent the peaks that are present in each spectrum and can be used as features to train ML algorithms. When training on the spectrum, the total number of features can exceed 1000 and are of high cardinality. This work demonstrates a method of using random forest (RF) classification and permutation feature importance to downselect the most important spectral bins. These features are representative of common peak locations in the training data. The use of the most important features determined by RF to reduce the dimensions of the training data set greatly enhanced the accuracy of a dense neural network.

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Document Details

Document Type
Technical Report
Publication Date
Sep 14, 2022
Accession Number
AD1180093

Entities

People

  • Brian C Hauck
  • Brian S. Ince
  • Kyle P. O'donnell
  • Mary M. Wade
  • Patrick C. Riley
  • Ruth Dereje
  • Samir V. Deshpande

Tags

Communities of Interest

  • Autonomy
  • Counter WMD
  • Energy and Power Technologies
  • Sensors
  • Space

DTIC Thesaurus Topics

  • Accuracy
  • Artificial Intelligence
  • Chemical Compounds
  • Chemical Detectors
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemistry
  • Data Sets
  • Detection
  • Detectors
  • Feature Selection
  • Information Processing
  • Information Systems
  • Machine Learning
  • Mass Spectrometry
  • Measurement
  • Neural Networks
  • Spectra
  • Spectrometry
  • Warning Systems

Fields of Study

  • Computer science

Readers

  • Analytical Chemistry
  • Graph Algorithms and Convex Optimization.
  • Neural Network Machine Learning.

Technology Areas

  • AI & ML
  • AI & ML - Neural Networks