Perfluorinated Alkyl Substance (PFAS) Analyte Testing and Additional Analytical Evaluation of Relevant Firefighting Foam Formulations and Samples

Abstract

In an effort to better understand the potential toxicity of new fluorine-free firefighting foams, a series of commercial laboratory analysis was performed to quantify potentially harmful chemical components. Analysis was conducted on 7 foam concentrates: 4 commercial-off-the-shelf (COTS) self-identified fluorine-free concentrates, 2 experimental fluorine-free foam concentrates made in a laboratory setting by a manufacturer and the U.S. Naval Research Laboratory, and one COTS fluorinated aqueous film forming foam (AFFF) for comparison to the other materials. Laboratory analysis included PFAS by DoD/DOE QSM Table B-15 Compliant Method, Extractable Organic Fluorine (EOF), EPA Method8270D, EPA Method 300/SW-846 Method 9056A, EPA Method 6010C, EPA Method 7470, GC/MS, and UPLC-QTOF-MS.

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Document Details

Document Type
Technical Report
Publication Date
Sep 28, 2022
Accession Number
AD1181396

Entities

People

  • Janice L Willey
  • Katherine M. Hinnant

Organizations

  • Naval Sea Systems Command
  • United States Naval Research Laboratory

Tags

DTIC Thesaurus Topics

  • Acids
  • Alkanes
  • Alkenes
  • Amines
  • Aromatic Polycyclic Hydrocarbons
  • Carboxylic Acids
  • Chemical Synthesis
  • Chemistry
  • Department Of Defense
  • Environmental Security
  • Ethers
  • Fatty Acids
  • Films
  • Materials
  • National Security
  • Organic Chemistry
  • Phenyl Ether
  • Polyethylene Glycols
  • Quality Control
  • Sampling
  • Standards
  • Sulfonic Acids
  • Test And Evaluation
  • Test Methods

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Environmental Engineering.
  • Fire Suppression Systems Design.