Evaluation of Chemical Agent Resistance of Polysiloxane-Based Films and Coatings

Abstract

Protective coatings or paints are required for all tactical U.S. Marine Corps and Army platforms including ground, aviation, and related support assets. These coatings are likely to be contaminated in a chemical warfare agent release; therefore, agent resistivity is a fundamental attribute for development of a coating system. The chemical agent resistance method (CARM) was developed to quantify agent sorption into the material. Through development of the CARM, it was recognized that multiple aspects of the coatings are not well understood, and work has now focused on understanding how coating chemistries and morphologies affect agent resistance. To better understand how to optimize coatings, researchers investigated chemical permeation and retention for coating materials using a family of polysiloxane-based coatings as a model coating system with adjustable materials properties. New techniques were implemented to quantify, understand, and control transport of chemical agents in coatings to enable the reformulation and implementation of new, superior coating systems that are applicable to topcoats or overcoat configurations. This knowledge will be used to establish a scientific basis for advancing future formulations with optimized chemical resistance.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 2022
Accession Number
AD1182634

Entities

People

  • Adam R. Hinkle
  • Anne Y. Walker
  • Brent A Mantooth
  • Christopher M. Stafford
  • Erick B. Iezzi
  • Eugene Camerino
  • Janlyn H. Eikenberg
  • Jeremiah Woodcock
  • Kristian M. Van De Voorde
  • Mark J. Varady
  • Melissa L. Sweat
  • Melissa S. Hulet
  • Thomas P. Pearl

Organizations

  • Defense Threat Reduction Agency
  • National Institute of Standards and Technology
  • Oak Ridge Institute for Science and Education
  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics
  • Counter WMD
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alkanes
  • Chemical Synthesis
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemistry
  • Composite Materials
  • Frequency Shift
  • Material Degradation Processes
  • Materials Laboratories
  • Materials Science
  • Materials Testing
  • Measurement
  • Mechanical Properties
  • Mechanics
  • Military Research
  • Polymer Chemistry
  • Polymer Matrix Composites
  • Polymeric Films
  • Quartz Crystal Microbalances
  • Standards

Readers

  • Critical Infrastructure Protection in CBRN and WMD Threats.
  • Surface Coatings Technology.
  • Theoretical Analysis.