Evaluating a Multi-Panel Air Cathode Through Electrochemical and Biotic Tests
Abstract
To scale up microbial fuel cells (MFCs), larger cathodes need to be developed that can use air directly, rather than dissolved oxygen, and have good electrochemical performance. A new type of cathode design was examined here that uses a window-pane approach with fifteen smaller cathodes welded to a single conductive metal sheet to maintain good electrical conductivity across the cathode with an increase in total area. Abiotic electrochemical tests were conducted to evaluate the impact of the cathode size (exposed areas of 7 cm, 33 cm, and 6200 cm) on performance for all cathodes having the same active catalyst material. Increasing the size of the exposed area of the electrodes to the electrolyte from 7 cm to 33 cm (a single cathode panel) decreased the cathode potential by 5 , and a further increase in size to 6200 cm using the multi-panel cathode reduced the electrode potential by 55 (at 0.6 A m), in a 50 mM phosphate buffer solution (PBS). In 85 L MFC tests with the largest cathode using wastewater as a fuel, the maximum power density based on polarization data was 0.083 0.006Wm using 22 brush anodes to fully cover the cathode, and 0.061 0.003Wm with 8 brush anodes (40 of cathode projected area) compared to 0.304 0.009Wm obtained in the 28 mL MFC. Recovering power from large MFCs will therefore be challenging, but several approaches identified in this study can be pursued to maintain performance when increasing the size of the electrodes.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 2019
- Accession Number
- AD1189287
Entities
People
- Bruce E. Logan
- David R Jones
- Deepak Pant
- Donald M. Cropek
- Emily Zikmund
- Jaewook Myung
- Martin A. Page
- Patrick J. Evans
- Ruggero Rossi
- Wulin Yang
- Yolanda Alvarez Gallego
Organizations
- Engineer Research and Development Center