Tiered In Vitro Toxicity Testing WP19-1338 Novel Additive Manufacturing Propellants

Abstract

The compounds ABID ([3-[5-(prop-2-enoyloxymethyl)isoxazol-3-yl]isoxazol-5-yl]methyl prop-2-enoate), n,n-bis(2-propyl) polyoxypropylenediamine (Jeffamine registered SD 2001 or SD2001) and glyceryl poly(oxypropylene)triamine (Jeffamine T5000 or T5000) are being assessed as components in potential new binder systems to replace isocyanate-based binders in energetic formulations. This study evaluated the toxicity of T5000, SD2001, and ABID in several in vitro test systems, including the Ames mutagenicity assay, the Microtox Acute Toxicity Test and skin sensitization. Data from the h-CLAT assay were also used to predict an acute oral toxicity hazard category. T5000, SD2001, and ABID were not mutagenic in Ames, ABID was predicted to be highly toxic (GHS category 1) to aquatic organisms and SD2001 and ABID were skin sensitizers. Data from this study are used to assist in making environment and health-based decisions regarding the design and selection of formulas and materials for further development of new munition compounds.

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Document Details

Document Type
Technical Report
Publication Date
Dec 31, 2022
Accession Number
AD1201479

Entities

People

  • Jorge Ruiz
  • Valerie H. Adams

Organizations

  • United States Army Center for Health Promotion and Preventive Medicine

Tags

DTIC Thesaurus Topics

  • Additive Manufacturing
  • Amino Acids
  • Bacteria
  • Chemical Compounds
  • Chemistry
  • Culture Media
  • Data Analysis
  • Environment
  • Environmental Protection
  • Hard Copy
  • Health Services
  • Instructions
  • Isocyanates
  • Liquid Chromatography
  • Manufacturing
  • Materials
  • Medical Personnel
  • Mutagenicity Tests
  • Public Health
  • Test Methods
  • Toxicity
  • Toxicology
  • Waste Management

Readers

  • Agricultural Chemistry/Soil Science
  • Astronomy/Astrophysics
  • Toxicology/Environmental Toxicology