Skin Sensitization Among Maintainers/Fabricators: Use of New Approach Methods to Identify Chemical Sensitizers and Determine Preliminary Candidate Surface Limits

Abstract

Allergic contact dermatitis (ACD) is an immunologic reaction to a dermal chemical exposure that, once triggered in an individual, will result in an allergic response following subsequent encounters with the allergen. Air Force (AF) epidemiological consultations have indicated that AF aircraft structural maintenance workers may experience ACD at elevated rates compared to other occupations. This project aims to better characterize the potential link between ACD and chemical exposure during AF operations by 1) evaluating the sensitization potential of priority AF-relevant chemicals using new approach methodologies, and 2) developing preliminary candidate surface guidelines (PCSGs, i.e., guidelines for the maximum concentrations of chemicals on workplace surfaces to prevent induction of dermal sensitization) for chemicals that are identified as sensitizers. Surface guidelines for known sensitizers were derived from available local lymph node assay (LLNA) and quantitative experimental human results in previously published literature. New approach methods (NAMs) including in chemico and in vitro assays (k-DPRA and KeratinoSens trademark) and in silico models (Derek Nexus (registered) and OECD QSAR Toolbox) were leveraged into an integrated approach to predict sensitizer status for 15 chemicals with unknown sensitization potential and four chemicals (limonene, xylene, benzaldehyde, methylglyoxal) with existing LLNA data. LLNA effective concentration values (EC3) were predicted from NAM data via the method of Natsch and Gerberick (2022). The derived EC3 values were used to calculate PCSGs, which can be used to compare to the presence of these chemicals on work surfaces to better understand the risk of Airmen, and workers in general, from developing ACD from occupational exposures.

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Document Details

Document Type
Technical Report
Publication Date
May 15, 2023
Accession Number
AD1207810

Entities

People

  • Allison Hilberer
  • Andrew Keebaugh
  • Argel Islas-robles
  • David R. Mattie
  • Elaine Merrill
  • Hans Raabe
  • Kayla Cantrell
  • Megan Steele
  • Rebecca Clewell
  • Yaroslav Chushak

Organizations

  • Air Force Research Laboratory
  • Henry M. Jackson Foundation for the Advancement of Military Medicine
  • Universal Energy Systems

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Air Force
  • Aldehydes
  • Alkanes
  • Alkenes
  • Cells
  • Chemical Synthesis
  • Chemistry
  • Dielectric Gases
  • Epidermis
  • Lymphatic System
  • Lymphocytes
  • Medical Personnel
  • Organic Chemistry
  • Rodents
  • Skin Diseases
  • Test Methods

Fields of Study

  • Environmental science

Readers

  • Allergy and Immunology.
  • Immunology
  • Toxicology/Environmental Toxicology