Probing the Surfaces of Atmospheric Organic Particles and the Implications for Climate Change, Air Quality, Visibility and Bioavailability

Abstract

The overall goal of this project was to elucidate the role of the surface in airborne particle systems during uptake of organic gases as well as to understand the 3-D composition in these systems in terms of differences between surface and bulk composition. Specific goals were: To develop and apply mass spectrometry techniques for differentiating molecular surface composition from that of the bulk for model laboratory systems, and apply these to more complex systems to understand surface and bulk composition during oxidation reactions. To understand gas-surface interactions in complex, multiphase systems in order to explain mechanisms of particle growth that lead to nonuniformities in composition between the surface and the bulk. Specific goals were: to develop and apply mass spectrometry techniques for differentiating molecular surface composition from that of the bulk for model laboratory systems, and apply these to more complex systems to understand surface and bulk composition during oxidation reactions, and to understand gas-surface interactions in complex, multiphase systems in order to explain mechanisms of particle growth that lead to nonuniformities in composition between the surface and the bulk.

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Document Details

Document Type
Technical Report
Publication Date
Dec 14, 2021
Accession Number
AD1208059

Entities

People

  • Barbara J. Finlayson-Pitts

Organizations

  • University of California, Irvine

Tags

Communities of Interest

  • Biomedical
  • C4I

DTIC Thesaurus Topics

  • Alkenes
  • Amines
  • Barometric Pressure
  • Chemical Synthesis
  • Chemistry
  • Ecology
  • Electrospray Ionization
  • Gas Surface Interactions
  • Malonic Acid
  • Mass Spectra
  • Mass Spectrometers
  • Mass Spectrometry
  • Measurement
  • Organic Chemistry
  • Organic Compounds
  • Spectrometry
  • Spectroscopy
  • Succinic Acid

Fields of Study

  • Environmental science

Readers

  • Aerosol Science/Aerosol Physics
  • Molecular and Cellular Biochemistry
  • Ocean-Atmosphere Mesoscale Modeling, Data Assimilation, and Flux Boundary Layers