Molecular Triplet Qubits
Abstract
Major Goals: 1.2. Specific Aims and Approach Aim 1: Create modular optically addressable qubits via synthesis of discrete tunable species a. Synthesize rigid ligands encapsulating first-row transition metals b. Measure ground-state electronic structure c. Optically measure electronic excited-state manifold d. Perform optically detected EPR experiments e. Use DFT/ CASSCF to simulate ground state, excited state, and EPR; compare to experiment Aim 2: Gain fundamental insight into the excited-state manifold of triplet species through hypothesis driven, rational synthetic modification. a. Iterate from previous results and synthesize new chemical families of synthetic targets b. Measure optical dynamics c. Parameterize and simulate finite-temperature spin dynamics d. Create synthetic design criteria for generating ideal excited-state manifold and dynamics Aim 3: Embed qubits based upon design principles established in previous aims into lattices a. Characterize ground-state properties of lattices b. Characterize excited-state properties.
Document Details
- Document Type
- Technical Report
- Publication Date
- Sep 17, 2021
- Accession Number
- AD1208962
Entities
People
- Donna E Freedman
- Timothy Berkelbach
Organizations
- Northwestern University