Antimonide Photonic Power Converters Assembled Through Micro-Transfer Printing

Abstract

This report details the design of a GaSb-based photonic power converter (PPC) which generates electrical power from eyesafe radiation. Devices were simulated in NRL MULTIBANDS (registered trademark) and optimized to maximize power conversion efficiency under 1550 nm monochromatic light. The highest efficiency was predicted for a device alloyed with a small amount of aluminum which increased the bandgap and maximized the voltage of the device. Simulated devices were grown by molecular beam epitaxy and processed in NRLs Nanoscience Institute. Although predicted performance of devices with AlGaSb was higher than GaSb, actual performance suffered due to low minority carrier lifetimes. This indicates that epitaxial material quality of low Al-containing antimonides needs optimization. In parallel to device optimization, the process for micro-transfer printing of antimonides was investigated using previously developed selective etch chemistries. Antimonide membranes were released from their native substrates and printed onto silicon handles. Increasing the temperature of the selective etch bath was found to decrease the time to release 200 x 200 micrometers membranes without adversely impacting etch selectivity.

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Document Details

Document Type
Technical Report
Publication Date
Sep 21, 2023
Accession Number
AD1211213

Entities

People

  • Margaret A. Stevens

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Band Gaps
  • Cells
  • Chemical Synthesis
  • Chemical Vapor Deposition
  • Chemistry
  • Citric Acid
  • Crystals
  • Efficiency
  • Electronics
  • Fabrication
  • Gallium Arsenides
  • Materials
  • Microscopes
  • Molecular Beam Epitaxy
  • Molecular Beams
  • Optoelectronics
  • Power Converters
  • Quantum Efficiency
  • Semiconductors
  • Solar Cells
  • Standards

Fields of Study

  • Materials science

Readers

  • Nanocomposite Materials Science
  • Optical Physics and Photonics.
  • Semiconductor Device Technology