Graphene in Cementitious Materials
Abstract
This project aims to determine the influence of laboratory-generated graphene (LGG) and commercial-grade graphene (CGG) on the chemical structure and compressive strength of graphene-cement mixtures. Determining the graphene-cement structure/processing/property relationships provides the most useful information for attaining the highest compressive strength. Graphene dose and particle size, speed of mixing, and dispersant agent were found to have important roles in graphene dispersion by affecting the adhesion forces between calcium silicate hydrate (CSH) gels and graphene surfaces that result in the enhanced strength of cement-graphene mixtures. X-ray diffraction (XRD), Raman, and scanning electron microscope (SEM) analyses were used to determine chemical microstructure, and compression testing for mechanical properties characterization, respectively. Based on observed results both LGG and CGG graphene cement mixtures showed an increase in the compressive strength over 7-, 14-, and 28-day age curing periods. Preliminary dispersion studies were performed to determine the most effective surfactant for graphene dispersion. Future studies will continue to research graphene cement mortar and graphene concrete composites using the most feasible graphene materials. These studies will prove invaluable for military programs, warfighter support, climate change, and civil works.
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 20, 2023
- Accession Number
- AD1217167
Entities
People
- Charles A. Weiss
- James Tour
- Jameson D. Shannon
- Jedadiah F. Burroughs
- Kevin M. Wyss
- Kyle L. Klaus
- Mine G. Ucak-astarlioglu
- Robert D. Moser
- Samuel L. Craig
- Stephen L. Murrell
Organizations
- Engineer Research and Development Center
- Rice University