Preparation of B-sigma-Metallocarboranes by Oxidative Addition; Model Intermediates for Transition Metal Catalyzed H-D Exchange in B-H Containing Species.
Abstract
A number of B-sigma-metallocarboranes have been prepared by oxidative addition of carboranyl boron-hydrogen bonds to an iridium complex. The complexes are models for intermediates in the transition metal catalyzed exchange of deuterium gas for hydrogen at terminal B-H bonds, and do themselves actively catalyze such exchange. Spectra are reported for 3-((PPh3)2Ir HCl)-1,2-C2B10H11.
Document Details
- Document Type
- Technical Report
- Publication Date
- Oct 31, 1974
- Accession Number
- ADA001082
Entities
People
- Elvin L. Hoel
- M. Frederick Hawthorne
Organizations
- University of California, Los Angeles