Scanning for Ferroelectricity in Polycrystalline Materials.

Abstract

A method has been developed which can scan rapidly for ferroelectricity in polycrystalline compounds. This consists of measuring the dielectric constant of a polycrystalline pellet as a function of temperature. If any dielectric anomalies are found where the dielectric and loss tangent peaks are independent of frequency, a solid/solid first order transition has been found. If the sample is held under a voltage gradient while the temperature is dropped through the transition temperature, charge storage shows poling of the sample and therefore ferroelectric behavior. The procedure was demonstrated on thiourea, a known ferroelectric. 2-Ethyl benzimidazole showed the same phenomena at a transition temperature of -90C and is probably a new ferroelectric material.

Document Details

Document Type
Technical Report
Publication Date
Nov 15, 1974
Accession Number
ADA001804

Entities

People

  • C. T. Hsu
  • M. Litt
  • P. Basu
  • S. M. Aharoni

Organizations

  • Case Western Reserve University

Tags

DTIC Thesaurus Topics

  • Benzimidazoles
  • Dielectric Permittivity
  • Ferroelectric Materials
  • Ferroelectricity
  • Frequency
  • Isotherms
  • Materials
  • Polycrystals
  • Scanning
  • Temperature Gradients
  • Transition Temperature
  • Transitions

Fields of Study

  • Physics

Readers

  • Analytical Chemistry
  • Materials Science and Engineering.