The Adsorption of Water Vapor on Fiberglas-E.

Abstract

Research was conducted to obtain adsorption data for water vapor on Fiberglas-E in order to understand the thermodynamical nature of adsorbate-adsorbent interfaces. A modification of Polanyi's potential theory considers changes of the nature of the adsorbent surface, eliminating controversial previous modifications of Polanyi's potential theory. The BET method was used to obtain the specific surface areas of E-glass. Surface free-energy of wetting was computed from the adsorption isotherm data depending upon temperature, surface geometry, and sample treatment. The isosteric heat of adsorption and entropy of adsorption were also computed from various adsorption isotherms. Seven adsorption isotherms have been completed. Calculation of isosteric heat of adsorption indicates the adsorbed state is between the solid and the liquid state - equivalent to the loss of one vibrational and one translational degree of freedom.

Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1971
Accession Number
ADA001821

Entities

People

  • R. J. Huang
  • T. D. Mcgee
  • T. Demirel

Organizations

  • Iowa State University

Tags

DTIC Thesaurus Topics

  • Adsorbates
  • Adsorbents
  • Adsorption
  • Energy
  • Free Energy
  • Geometry
  • Isotherms
  • Potential Theory
  • Vapors
  • Water Vapor

Readers

  • Agricultural Chemistry/Soil Science
  • Materials Science and Engineering.
  • Surface Coatings Technology.