Free Energy Determinations by Solid Galvanic Cell Measurements for Selected Metal, Metal-Fluoride Reactions.

Abstract

Free energies for displacement reactions involving metals and their fluorides have been measured at various temperatures by the solid electrolyte galvanic cell technique. The results are presented in the form of cell emf vs temperature equations. By combining these results with data from the literature, standard free energies of formation data for the fluorides studied have also been calculated and tabulated for use in conventional thermodynamic calculations.

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1972
Accession Number
ADA001823

Entities

People

  • J. W. Patterson
  • W. H. Skelton

Organizations

  • Iowa State University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Cells
  • Displacement
  • Displacement Reactions
  • Electrochemical Cells
  • Electrolytes
  • Energy
  • Equations
  • Fluorides
  • Free Energy
  • Literature
  • Measurement
  • Standards

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies