Electronic and Magnetic Properties of High Temperature Electrolytes.
Abstract
Measurements are reported on the electrical conductance in the Cs-CsCl and Rb-RbCl molten systems as a function of composition and temperature. The solutions are semiconducting at low metal concentration and become metallic with increasing concentration. Excess free energies for solution of metal in salt are evaluated from freezing point data, and are large and positive for the Cs-CsCl and Rb-RbCl systems. Electron spin resonance has been observed in the molten Na-NaCl system. These observations are interpreted in terms of an F-center model of the electron in metal-molten salt solutions.
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 26, 1974
- Accession Number
- ADA004136
Entities
People
- Norman H. Nachtrieb
Organizations
- University of Chicago