Selective Catalytic Oligomerizations and Hydrogenations Using Polymer-Anchored Complexes of Ni and Ir.
Abstract
Polystyrene-divinylbenzene resin-anchored Ni(CO)2(PPh3)2 has been used to selectively oligomerize butadiene to either 4-vinyl-cyclohexene or 1,5-cyclooctadiene. Anchored Ir(Cl) (CO) (PPh3)2 selectively catalyzes the hydrogenation of 1,5-cyclooctadiene to cyclooctene. The activity of these catalysts in some cases surpasses that of their homogeneous counterparts under identical conditions.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 15, 1975
- Accession Number
- ADA004944
Entities
People
- Charles U. Pittman Jr.
- Stephen E. Jacobson
Organizations
- University of Alabama